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42CrMo4

1.7225

Chromium-molybdenum alloy special steel for quenching and tempering · EN ISO 683-2 / ISO 683-2 · EN 10277 for bright steel products · EN 10250-3 for open-die forgings · EN 10297-1 for seamless mechanical-engineering tubes

42CrMo4 (1.7225) is a medium-carbon chromium-molybdenum engineering steel selected for components requiring substantially greater hardenability, strength and fatigue resistance than plain-carbon steels. Its useful properties are created by heat treatment: the grade name alone does not establish strength, hardness or toughness. Section size, ruling section, delivery condition, hardenability option and the governing product standard must therefore be defined when ordering or assessing a component.

Overview

Designation system
European steel name to EN 10027-1; material number to EN 10027-2
Product forms
Hot-formed semi-finished products, Bars, Wire rod, Finished flat products, Hammer and drop forgings, Bright steel products under the applicable product standard, Seamless tubes under the applicable tube standard
Condition
Untreated (+U), Treated to improve shearability (+S), Soft annealed (+A), Quenched and tempered (+QT), Specified hardenability (+H, +HH or +HL), Flame or induction hardened after suitable core heat treatment
Density
7.8 g/cm³ (Representative physical value, not a chemical or acceptance requirement of the grade.)

What the designation defines

42CrMo4 is a direct-hardening alloy steel rather than a structural steel strength class. The designation primarily identifies a controlled chemical composition: approximately 0.42% carbon with chromium and molybdenum additions. Chromium increases hardenability and wear response; molybdenum supports through-section hardening and reduces susceptibility to temper embrittlement. The grade is normally used with a tempered-martensitic or related quenched-and-tempered microstructure.

A certificate stating only “42CrMo4” does not establish a finished component strength. Delivery condition, dimensions, heat-treatment batch, test location and applicable product standard are essential parts of the material definition.

Standards and product-form boundaries

Where the designation is encountered
Standard or specificationRelevant scopePractical consequence
EN ISO 683-2 / ISO 683-2Hot-formed semi-finished products, bars, wire rod, finished flat products and hammer or drop forgingsPrincipal source for composition, delivery conditions, hardenability options and dimension-dependent +QT properties
EN 10277Bright steel productsDimensional tolerances, surface condition, processing route and properties must be taken from the bright-product specification rather than assumed from hot-rolled bar
EN 10250-3Open-die alloy-special-steel forgingsApplies forging-specific delivery, testing and heat-treatment provisions
EN 10297-1Seamless circular tubes for mechanical and general engineering purposesTube dimensions, tests and property requirements are product-specific
EN 10305-1Seamless cold-drawn precision tubesCold drawing and the specified tube delivery condition materially affect properties
EN 10263-4Rod, bars and wire for cold heading and cold extrusionControls material intended for a manufacturing route outside the main scope of ISO 683-2
EN 10132-3Cold-rolled narrow strip for heat treatmentUse strip-specific requirements and thickness-dependent properties
EN 10269Steels and nickel alloys for fasteners with specified elevated- or low-temperature properties42CrMo4 chemistry alone does not demonstrate compliance with a temperature-rated fastener specification

EN 10083-3 is the commonly cited predecessor for alloy steels for quenching and tempering. Existing drawings may legitimately reference a particular historical edition, but new procurement should identify the required current standard or explicitly retain the legacy specification when contractually necessary. Requirements from different product standards must not be combined into a single apparent property set.

Chemical composition

Cast-analysis limits for 42CrMo4 under ISO 683-2
ElementMass fraction (%)Metallurgical significance
C0.38–0.45Strength, hardness and martensitic response; also increases weld-cracking risk
Si0.10–0.40Deoxidation and solid-solution strengthening; lower silicon may be used with alternative deoxidation practice
Mn0.60–0.90Hardenability and deoxidation
P≤0.025Restricted residual; lower levels may be specified for demanding toughness or fatigue applications
S≤0.035Maximum for the standard grade; machinability and cleanliness depend strongly on actual sulfur and inclusion control
Cr0.90–1.20Primary hardenability and surface-hardening alloy addition
Mo0.15–0.30Hardenability, tempering response and resistance to softening
Cu≤0.40Maximum residual limit

These are cast-analysis limits. Permitted product-analysis deviations are separately defined by the standard. Product analysis must be specified at enquiry and order if independent verification is required.

Delivery condition and heat treatment

Conditions important to purchasing and processing
ConditionMeaningKey requirement or consequence
+UUntreatedProperties reflect the manufacturing route and are not the final quenched-and-tempered properties
+STreated to improve shearabilityMaximum hardness for 42CrMo4 is 255 HBW; suitability depends on composition and dimensions
+ASoft annealedMaximum hardness is 241 HBW under ISO 683-2; normally preferred for extensive machining or cold shearing
+QTQuenched and temperedMechanical properties apply by ruling-section range and prescribed test-piece location
+HNormal specified Jominy hardenability bandUseful where predictable heat-treatment response is more important than acceptance by initial delivery hardness alone
+HHUpper narrowed hardenability bandRestricts supply toward the upper part of the normal hardenability band
+HLLower narrowed hardenability bandRestricts supply toward the lower part of the normal hardenability band
Standard heat-treatment framework
OperationTemperature or mediumComment
Austenitize for hardening820–860 °CLower temperatures are generally associated with water quenching and upper temperatures with oil quenching
QuenchOil or waterSelection must account for section size, required core transformation, geometry, residual stress and cracking risk
Temper540–680 °CSelect to achieve the specified strength and toughness; final properties require validation on the actual ruling section
Jominy test austenitizing840 ± 5 °CStandardized condition for end-quench hardenability verification
Low-temperature stress relief after induction or flame hardening150–180 °C for about 1 hourCondition associated with the standardized minimum surface-hardness value

Heat-treatment response is section dependent. The surface can transform rapidly while the core of a large component cools too slowly to form the same microstructure. This is why the standard bases mechanical properties on the ruling section rather than merely the overall nominal diameter or stock size. Manufacturer claims for through-hardening diameter are process- and chemistry-dependent and should not be treated as universal grade requirements.

Mechanical properties in the quenched-and-tempered condition

ISO 683-2 +QT requirements by ruling section
Round ruling section d / flat-product thickness tRp0.2 minimum (MPa)Rm (MPa)A minimum (%)Z minimum (%)KV2 minimum (J)
d ≤16 mm / t ≤8 mm9001100–13001040Not specified
16<d≤40 mm / 8<t≤20 mm7501000–1200114535
40<d≤100 mm / 20<t≤60 mm650900–1100125035
100<d≤160 mm / 60<t≤100 mm550800–950135035
160<d≤250 mm / 100<t≤160 mm500750–900145535

Values apply to standardized test pieces taken from prescribed locations. A is based on proportional gauge length. Z values are optional and must be agreed at enquiry and order. KV2 is the average of three longitudinal Charpy V-notch results using a 2 mm striker radius; no individual result may be below 70% of the specified minimum average.

The progressive reduction in specified strength with increasing ruling section reflects achievable cooling rate and microstructural uniformity. A small test coupon heat treated separately from a large component may substantially overstate the component's core properties. For critical parts, the heat-treatment qualification, test location and sacrificial prolongation or integral test material should be agreed before manufacture.

Hardenability and localized surface hardening

42CrMo4 is valued primarily for hardenability rather than corrosion resistance or inherent as-supplied strength. ISO 683-2 permits ordering with normal or narrowed Jominy bands. Specifying +H, +HH or +HL is particularly useful for serial heat-treated components where variations in core hardness, distortion or quench response must be controlled more closely than broad chemistry limits alone permit.

Normal hardenability band for 42CrMo4 +H
Distance from quenched end (mm; values in HRC)1.5357911131520253035404550
Normal hardenability band for 42CrMo4 +H53–6153–6152–6151–6049–6043–5940–5937–5834–5632–5331–5130–4830–4729–4629–45

Jominy limits under the standard test condition; they do not directly equal the hardness profile of a finished component.

Flame or induction hardening can provide a wear-resistant martensitic surface over a quenched-and-tempered core. The standardized minimum surface hardness is 53 HRC for appropriately processed sections up to 250 mm diameter. Effective case depth, transition hardness, retained stress and distortion are process-design variables and must be specified separately. Surface decarburization can prevent the required hardness from being achieved.

42CrMo4 is not a conventional low-carbon carburizing grade. If a deep carburized case with a tough low-carbon core is required, a purpose-designed case-hardening steel should normally be evaluated instead.

Machining, forming and welding

Machinability is strongly condition dependent. The soft-annealed condition is appropriate for heavy stock removal; quenched-and-tempered stock requires tooling and parameters matched to its actual hardness. Where enhanced chip control is essential, 42CrMoS4 or a calcium-treated proprietary machinability variant may be considered, but sulfur modification and inclusion engineering can affect transverse ductility, polishability and fatigue performance.

Hot forging is practical, but the forging supplier must control finishing temperature, cooling and subsequent heat treatment to avoid coarse grain, excessive scale or decarburization. Final properties should be established after the last property-controlling heat treatment, not inferred from the starting billet certificate.

Welding requires specific procedure development because the carbon and alloy content create a hardenable heat-affected zone and significant hydrogen-cracking susceptibility. Low-hydrogen consumables, controlled preheat and interpass temperature, appropriate heat input and controlled cooling are normally required. A representative high-restraint procedure may use approximately 250 °C preheat, but this is not a universal set point: the WPS must account for actual composition, thickness, restraint, initial heat-treatment condition, filler strength and service requirements. Tempering or another qualified postweld heat treatment may be necessary where a brittle HAZ or loss of the original +QT property balance is unacceptable.

Welding can locally erase or alter the certified quenched-and-tempered condition. Matching weld-metal tensile strength alone does not demonstrate adequate HAZ toughness, fatigue performance or resistance to delayed cracking.

Applications and engineering limitations

Typical uses include shafts, axles, spindles, pins, highly loaded bolts, connecting rods, steering and drivetrain parts, gear blanks, tooling supports and general machine components exposed to combined bending, torsion, impact or fatigue. Suitability derives from the selected heat-treated condition and component design rather than from the designation alone.

42CrMo4 is not stainless and requires suitable corrosion protection where atmospheric, aqueous or chemical attack matters. The base grade also does not carry a general low-temperature toughness class, pressure-equipment approval, hydrogen-service qualification, fracture-toughness guarantee or elevated-temperature design strength. Such requirements must come from the applicable component specification, product standard and qualification program.

Ordering and acceptance checklist

Information that should be fixed before purchase
ItemWhat to specify or verify
Governing documentExact product standard and edition required by the drawing, code or contract
Designation42CrMo4 / 1.7225, including +A, +S, +QT or hardenability suffix where applicable
Product form and dimensionsBar, plate, forging, tube, bright product or other form, including tolerances and surface condition
Ruling sectionDetermine the mechanical-property range applicable to the finished or heat-treated geometry
Heat treatmentWhether performed by the steelmaker, stockholder, forger, machinist or final component manufacturer
Mechanical testingRequired tensile, hardness and impact tests; orientation, location, test temperature and acceptance values
HardenabilityWhether ordinary chemistry supply is sufficient or +H, +HH or +HL control is required
Metallurgical qualityAny agreed grain-size verification, inclusion limits, ultrasonic testing, macro examination or special cleanliness
Surface integrityDecarburization limit, defect-removal rules, surface class and machining allowance
CertificationInspection document type, commonly EN 10204 type 3.1 or project-specific certification
TraceabilityHeat and heat-treatment-batch traceability through cutting, forging, machining and final testing
Special serviceCorrosion, fatigue, low temperature, hydrogen exposure, pressure service or regulatory requirements requiring additional qualification

For stock offered as “42CrMo4 QT,” compare the certified property range, test location and original ruling section with the intended component. A quoted hardness or tensile band from a distributor is not automatically the ISO 683-2 requirement for every size or product form.

Sources

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42CrMo4 | MetalMate Grade Guide