42CrMo4
1.7225
Chromium-molybdenum alloy special steel for quenching and tempering · EN ISO 683-2 / ISO 683-2 · EN 10277 for bright steel products · EN 10250-3 for open-die forgings · EN 10297-1 for seamless mechanical-engineering tubes
42CrMo4 (1.7225) is a medium-carbon chromium-molybdenum engineering steel selected for components requiring substantially greater hardenability, strength and fatigue resistance than plain-carbon steels. Its useful properties are created by heat treatment: the grade name alone does not establish strength, hardness or toughness. Section size, ruling section, delivery condition, hardenability option and the governing product standard must therefore be defined when ordering or assessing a component.
- EN ISO 683-2 / ISO 683-2Defining standard · The principal specification for hot-formed products intended for quenching and tempering; former EN 10083-3 references remain common in drawings and stock lists
- 0.38–0.45% CNominal carbon level · Enables high strength and surface hardness but makes welding significantly more demanding than for ordinary structural steels
- Rm 750–1300 MPaQuenched-and-tempered strength · Specified range depends on ruling section; it is not a universal property of every 42CrMo4 product
- 820–860 °C, oil or water quenchStandard hardening treatment · Quench medium and process must be selected for section size, geometry, distortion and cracking risk
- 540–680 °CStandard tempering range · Final tempering practice controls the strength–toughness balance
- Minimum 53 HRCSurface hardening capability · Standard value after flame or induction hardening under the specified conditions; decarburization can reduce measured surface hardness
Overview
- Designation system
- European steel name to EN 10027-1; material number to EN 10027-2
- Product forms
- Hot-formed semi-finished products, Bars, Wire rod, Finished flat products, Hammer and drop forgings, Bright steel products under the applicable product standard, Seamless tubes under the applicable tube standard
- Condition
- Untreated (+U), Treated to improve shearability (+S), Soft annealed (+A), Quenched and tempered (+QT), Specified hardenability (+H, +HH or +HL), Flame or induction hardened after suitable core heat treatment
- Density
- 7.8 g/cm³ (Representative physical value, not a chemical or acceptance requirement of the grade.)
What the designation defines
42CrMo4 is a direct-hardening alloy steel rather than a structural steel strength class. The designation primarily identifies a controlled chemical composition: approximately 0.42% carbon with chromium and molybdenum additions. Chromium increases hardenability and wear response; molybdenum supports through-section hardening and reduces susceptibility to temper embrittlement. The grade is normally used with a tempered-martensitic or related quenched-and-tempered microstructure.
A certificate stating only “42CrMo4” does not establish a finished component strength. Delivery condition, dimensions, heat-treatment batch, test location and applicable product standard are essential parts of the material definition.
Standards and product-form boundaries
| Standard or specification | Relevant scope | Practical consequence |
|---|---|---|
| EN ISO 683-2 / ISO 683-2 | Hot-formed semi-finished products, bars, wire rod, finished flat products and hammer or drop forgings | Principal source for composition, delivery conditions, hardenability options and dimension-dependent +QT properties |
| EN 10277 | Bright steel products | Dimensional tolerances, surface condition, processing route and properties must be taken from the bright-product specification rather than assumed from hot-rolled bar |
| EN 10250-3 | Open-die alloy-special-steel forgings | Applies forging-specific delivery, testing and heat-treatment provisions |
| EN 10297-1 | Seamless circular tubes for mechanical and general engineering purposes | Tube dimensions, tests and property requirements are product-specific |
| EN 10305-1 | Seamless cold-drawn precision tubes | Cold drawing and the specified tube delivery condition materially affect properties |
| EN 10263-4 | Rod, bars and wire for cold heading and cold extrusion | Controls material intended for a manufacturing route outside the main scope of ISO 683-2 |
| EN 10132-3 | Cold-rolled narrow strip for heat treatment | Use strip-specific requirements and thickness-dependent properties |
| EN 10269 | Steels and nickel alloys for fasteners with specified elevated- or low-temperature properties | 42CrMo4 chemistry alone does not demonstrate compliance with a temperature-rated fastener specification |
EN 10083-3 is the commonly cited predecessor for alloy steels for quenching and tempering. Existing drawings may legitimately reference a particular historical edition, but new procurement should identify the required current standard or explicitly retain the legacy specification when contractually necessary. Requirements from different product standards must not be combined into a single apparent property set.
Chemical composition
| Element | Mass fraction (%) | Metallurgical significance |
|---|---|---|
| C | 0.38–0.45 | Strength, hardness and martensitic response; also increases weld-cracking risk |
| Si | 0.10–0.40 | Deoxidation and solid-solution strengthening; lower silicon may be used with alternative deoxidation practice |
| Mn | 0.60–0.90 | Hardenability and deoxidation |
| P | ≤0.025 | Restricted residual; lower levels may be specified for demanding toughness or fatigue applications |
| S | ≤0.035 | Maximum for the standard grade; machinability and cleanliness depend strongly on actual sulfur and inclusion control |
| Cr | 0.90–1.20 | Primary hardenability and surface-hardening alloy addition |
| Mo | 0.15–0.30 | Hardenability, tempering response and resistance to softening |
| Cu | ≤0.40 | Maximum residual limit |
These are cast-analysis limits. Permitted product-analysis deviations are separately defined by the standard. Product analysis must be specified at enquiry and order if independent verification is required.
Delivery condition and heat treatment
| Condition | Meaning | Key requirement or consequence |
|---|---|---|
| +U | Untreated | Properties reflect the manufacturing route and are not the final quenched-and-tempered properties |
| +S | Treated to improve shearability | Maximum hardness for 42CrMo4 is 255 HBW; suitability depends on composition and dimensions |
| +A | Soft annealed | Maximum hardness is 241 HBW under ISO 683-2; normally preferred for extensive machining or cold shearing |
| +QT | Quenched and tempered | Mechanical properties apply by ruling-section range and prescribed test-piece location |
| +H | Normal specified Jominy hardenability band | Useful where predictable heat-treatment response is more important than acceptance by initial delivery hardness alone |
| +HH | Upper narrowed hardenability band | Restricts supply toward the upper part of the normal hardenability band |
| +HL | Lower narrowed hardenability band | Restricts supply toward the lower part of the normal hardenability band |
| Operation | Temperature or medium | Comment |
|---|---|---|
| Austenitize for hardening | 820–860 °C | Lower temperatures are generally associated with water quenching and upper temperatures with oil quenching |
| Quench | Oil or water | Selection must account for section size, required core transformation, geometry, residual stress and cracking risk |
| Temper | 540–680 °C | Select to achieve the specified strength and toughness; final properties require validation on the actual ruling section |
| Jominy test austenitizing | 840 ± 5 °C | Standardized condition for end-quench hardenability verification |
| Low-temperature stress relief after induction or flame hardening | 150–180 °C for about 1 hour | Condition associated with the standardized minimum surface-hardness value |
Heat-treatment response is section dependent. The surface can transform rapidly while the core of a large component cools too slowly to form the same microstructure. This is why the standard bases mechanical properties on the ruling section rather than merely the overall nominal diameter or stock size. Manufacturer claims for through-hardening diameter are process- and chemistry-dependent and should not be treated as universal grade requirements.
Mechanical properties in the quenched-and-tempered condition
| Round ruling section d / flat-product thickness t | Rp0.2 minimum (MPa) | Rm (MPa) | A minimum (%) | Z minimum (%) | KV2 minimum (J) |
|---|---|---|---|---|---|
| d ≤16 mm / t ≤8 mm | 900 | 1100–1300 | 10 | 40 | Not specified |
| 16<d≤40 mm / 8<t≤20 mm | 750 | 1000–1200 | 11 | 45 | 35 |
| 40<d≤100 mm / 20<t≤60 mm | 650 | 900–1100 | 12 | 50 | 35 |
| 100<d≤160 mm / 60<t≤100 mm | 550 | 800–950 | 13 | 50 | 35 |
| 160<d≤250 mm / 100<t≤160 mm | 500 | 750–900 | 14 | 55 | 35 |
Values apply to standardized test pieces taken from prescribed locations. A is based on proportional gauge length. Z values are optional and must be agreed at enquiry and order. KV2 is the average of three longitudinal Charpy V-notch results using a 2 mm striker radius; no individual result may be below 70% of the specified minimum average.
The progressive reduction in specified strength with increasing ruling section reflects achievable cooling rate and microstructural uniformity. A small test coupon heat treated separately from a large component may substantially overstate the component's core properties. For critical parts, the heat-treatment qualification, test location and sacrificial prolongation or integral test material should be agreed before manufacture.
Hardenability and localized surface hardening
42CrMo4 is valued primarily for hardenability rather than corrosion resistance or inherent as-supplied strength. ISO 683-2 permits ordering with normal or narrowed Jominy bands. Specifying +H, +HH or +HL is particularly useful for serial heat-treated components where variations in core hardness, distortion or quench response must be controlled more closely than broad chemistry limits alone permit.
| Distance from quenched end (mm; values in HRC) | 1.5 | 3 | 5 | 7 | 9 | 11 | 13 | 15 | 20 | 25 | 30 | 35 | 40 | 45 | 50 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Normal hardenability band for 42CrMo4 +H | 53–61 | 53–61 | 52–61 | 51–60 | 49–60 | 43–59 | 40–59 | 37–58 | 34–56 | 32–53 | 31–51 | 30–48 | 30–47 | 29–46 | 29–45 |
Jominy limits under the standard test condition; they do not directly equal the hardness profile of a finished component.
Flame or induction hardening can provide a wear-resistant martensitic surface over a quenched-and-tempered core. The standardized minimum surface hardness is 53 HRC for appropriately processed sections up to 250 mm diameter. Effective case depth, transition hardness, retained stress and distortion are process-design variables and must be specified separately. Surface decarburization can prevent the required hardness from being achieved.
42CrMo4 is not a conventional low-carbon carburizing grade. If a deep carburized case with a tough low-carbon core is required, a purpose-designed case-hardening steel should normally be evaluated instead.
Machining, forming and welding
Machinability is strongly condition dependent. The soft-annealed condition is appropriate for heavy stock removal; quenched-and-tempered stock requires tooling and parameters matched to its actual hardness. Where enhanced chip control is essential, 42CrMoS4 or a calcium-treated proprietary machinability variant may be considered, but sulfur modification and inclusion engineering can affect transverse ductility, polishability and fatigue performance.
Hot forging is practical, but the forging supplier must control finishing temperature, cooling and subsequent heat treatment to avoid coarse grain, excessive scale or decarburization. Final properties should be established after the last property-controlling heat treatment, not inferred from the starting billet certificate.
Welding requires specific procedure development because the carbon and alloy content create a hardenable heat-affected zone and significant hydrogen-cracking susceptibility. Low-hydrogen consumables, controlled preheat and interpass temperature, appropriate heat input and controlled cooling are normally required. A representative high-restraint procedure may use approximately 250 °C preheat, but this is not a universal set point: the WPS must account for actual composition, thickness, restraint, initial heat-treatment condition, filler strength and service requirements. Tempering or another qualified postweld heat treatment may be necessary where a brittle HAZ or loss of the original +QT property balance is unacceptable.
Welding can locally erase or alter the certified quenched-and-tempered condition. Matching weld-metal tensile strength alone does not demonstrate adequate HAZ toughness, fatigue performance or resistance to delayed cracking.
Applications and engineering limitations
Typical uses include shafts, axles, spindles, pins, highly loaded bolts, connecting rods, steering and drivetrain parts, gear blanks, tooling supports and general machine components exposed to combined bending, torsion, impact or fatigue. Suitability derives from the selected heat-treated condition and component design rather than from the designation alone.
42CrMo4 is not stainless and requires suitable corrosion protection where atmospheric, aqueous or chemical attack matters. The base grade also does not carry a general low-temperature toughness class, pressure-equipment approval, hydrogen-service qualification, fracture-toughness guarantee or elevated-temperature design strength. Such requirements must come from the applicable component specification, product standard and qualification program.
Ordering and acceptance checklist
| Item | What to specify or verify |
|---|---|
| Governing document | Exact product standard and edition required by the drawing, code or contract |
| Designation | 42CrMo4 / 1.7225, including +A, +S, +QT or hardenability suffix where applicable |
| Product form and dimensions | Bar, plate, forging, tube, bright product or other form, including tolerances and surface condition |
| Ruling section | Determine the mechanical-property range applicable to the finished or heat-treated geometry |
| Heat treatment | Whether performed by the steelmaker, stockholder, forger, machinist or final component manufacturer |
| Mechanical testing | Required tensile, hardness and impact tests; orientation, location, test temperature and acceptance values |
| Hardenability | Whether ordinary chemistry supply is sufficient or +H, +HH or +HL control is required |
| Metallurgical quality | Any agreed grain-size verification, inclusion limits, ultrasonic testing, macro examination or special cleanliness |
| Surface integrity | Decarburization limit, defect-removal rules, surface class and machining allowance |
| Certification | Inspection document type, commonly EN 10204 type 3.1 or project-specific certification |
| Traceability | Heat and heat-treatment-batch traceability through cutting, forging, machining and final testing |
| Special service | Corrosion, fatigue, low temperature, hydrogen exposure, pressure service or regulatory requirements requiring additional qualification |
For stock offered as “42CrMo4 QT,” compare the certified property range, test location and original ruling section with the intended component. A quoted hardness or tensile band from a distributor is not automatically the ISO 683-2 requirement for every size or product form.
Sources
- ISO 683-2:2016 — Heat-treatable steels, alloy steels and free-cutting steels — Part 2: Alloy steels for quenching and temperingInternational Organization for Standardization
- ISO 683-2:2016 previewISO reproduction hosted by iTeh/SIST
- ISO/TR 20172:2020 — Welding grouping systems for European materialsInternational Organization for Standardization
- 42CrMo4 Steel Grade Data SheetOvako
- What is the procedure for welding En19?TWI
- 1.7225 — 42CrMo4 Material DatabaseWalzwerke Einsal
- 42CrMo4 +A under EN 10305-1Mannesmann / Salzgitter
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