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16Mo3

1.5415

Molybdenum-alloyed ferritic steel for pressure purposes with specified elevated-temperature properties · EN 10028-2:2017 — flat products for pressure purposes · EN 10216-2:2024 — seamless pressure tubes · EN 10217-2:2019 and EN 10217-5:2019 — welded pressure tubes · EN 10222-2:2017+A1:2021 — pressure-purpose forgings · EN 10273:2016 — hot-rolled pressure-purpose bars · EN 10253-2:2021 — butt-welding fittings

16Mo3 is a weldable, approximately 0.3% molybdenum ferritic pressure-equipment steel used where carbon steels no longer provide sufficient strength or creep resistance at elevated temperature. Its requirements are product-standard, dimension and condition dependent: EN 10028-2 defines flat products, while tubes, forgings, bars and fittings must be ordered to their own standards and must not be assumed to share the plate property table.

Overview

Designation system
EN steel name according to EN 10027-1; steel number according to EN 10027-2
Product forms
Plate, sheet and strip, Seamless tube and pipe, Electric-welded and submerged-arc-welded tube, Forgings, Hot-rolled bars, Butt-welding fittings
Condition
Normalized (+N), Normalized and tempered (+NT), permitted for some flat products at the manufacturer's discretion, Normalizing rolled where permitted by the governing product standard, Untreated only by agreement, with properties verified on appropriately heat-treated test pieces
Density
7.85 g/cm³ (Representative room-temperature value; not a grade acceptance requirement.)

What the designation covers

16Mo3 is an alloy special steel whose name is based on chemical composition rather than minimum yield strength. The leading number indicates an approximate carbon level of 0.16%, while Mo identifies the intentional molybdenum addition. The combination of moderate carbon and approximately 0.3% Mo produces a normalized ferrite-pearlite structure with better elevated-temperature strength and creep behaviour than common P…GH carbon-manganese pressure steels.

Product form determines the governing requirements
Product formRelevant specificationPractical consequence
Plate, sheet and stripEN 10028-2:2017 together with EN 10028-1Plate chemistry, transverse mechanical properties, delivery condition and options are defined here.
Seamless tubeEN 10216-2:2024Tube properties depend on wall thickness, test category, orientation, manufacture and heat treatment; plate values do not apply.
Electric-welded tubeEN 10217-2:2019Includes requirements specific to the tube body and longitudinal weld.
Submerged-arc-welded tubeEN 10217-5:2019Includes manufacturing-route, weld and inspection requirements not covered by the plate standard.
ForgingsEN 10222-2:2017+A1:2021Mechanical properties and testing depend on the forging standard, ruling section and heat treatment.
Hot-rolled barEN 10273:2016Used for pressure-purpose components such as machined parts and some flange applications; bar requirements apply.
Butt-welding fittingsEN 10253-2:2021Component manufacture, geometry, heat treatment and testing are controlled by the fitting standard.

A purchase order stating only “16Mo3” is incomplete. It should identify the product standard, dimensions, delivery condition, inspection document, required options and the applicable equipment or piping code.

Composition and metallurgical significance

EN 10028-2 cast analysis for 16Mo3 flat products
ElementRequirement, mass %Significance
C0.12–0.20Balances strength, heat-treatment response, formability and weldability.
Si≤0.35Deoxidizing residual; excessive silicon is restricted.
Mn0.40–0.90Contributes to strength and hardenability.
P≤0.025Restricted for toughness and fabrication quality.
S≤0.010Low maximum supports toughness and weld quality.
N≤0.012Controlled interstitial content.
Cr≤0.30Residual limit rather than a defining chromium addition.
Cu≤0.30A lower Cu limit or a Cu-plus-Sn restriction can be agreed where hot formability is important.
Mo0.25–0.35Defining alloy addition for elevated-temperature and creep performance.
Ni≤0.30Residual limit.
AlReport cast valueThe aluminium content must be determined and stated in the inspection document; EN 10028-2 does not give a normal composition range for this grade.

The standard limits are cast-analysis requirements. Product analysis is subject to separate permissible deviations and should not be compared directly with cast limits without applying those tolerances. EN 10028-2 does not specify a general maximum carbon-equivalent requirement for 16Mo3 plate; weldability assessment must therefore use the actual certified composition, product thickness, restraint, heat input and applicable fabrication standard.

Delivery condition and heat treatment

For EN 10028-2 flat products, the usual condition is normalized (+N). Normalizing rolling may replace furnace normalizing at the manufacturer's discretion. Additional testing after simulated normalizing can be agreed when the purchaser needs confirmation that the properties will survive a later normalizing operation. The grade may also be supplied normalized and tempered (+NT) at the manufacturer's discretion.

Heat-treatment guidance for EN 10028-2 flat products
OperationGuidanceImportant qualification
Normalizing890–950°CAfter the temperature has been attained throughout the cross-section, further holding is generally unnecessary and should be avoided.
Tempering after normalizing590–650°C in certain casesNot the routine delivery treatment for every product; use only under an approved manufacturing or fabrication procedure.
Untreated deliveryPossible by agreementTesting is performed on test pieces in the usual heat-treated condition, so as-delivered properties must not be inferred from the certificate without checking the stated delivery condition.
Post-fabrication heat treatmentControlled by the fabrication and pressure-equipment codeThe accumulated time-temperature exposure can reduce strength; all intended heat-treatment cycles should be communicated to the material producer.
EN 10028-2 time-temperature parameter for stress-relief exposure
P = Ts × (20 + log10 t) × 10^-3
Ts is stress-relieving temperature in kelvin and t is holding time in hours. For 16Mo3, Pcrit is 17.5; reference threshold combinations are approximately 600°C for 1 h or 590°C for 2 h. Exceeding Pcrit is not an automatic prohibition, but the purchaser should inform the producer and consider tests on simulated heat-treated samples.

EN 10028-2 plate properties at room temperature

Transverse tensile requirements in the normalized condition
Nominal thickness t, mmMinimum ReH, MPaRm, MPaMinimum elongation A, %
≤16275440–59022
>16 to 40270440–59022
>40 to 60260440–59022
>60 to 100240430–58022
>100 to 150220420–57022
>150 to 250210410–57022
Charpy V-notch requirements for plate
Test temperatureMinimum average KV2Status
+20°C31 JStandard requirement; 40 J may be agreed at enquiry and order.
0°CBy agreementNo automatic value for 16Mo3.
−20°CBy agreementNo automatic value for 16Mo3.

The tabulated EN 10028-2 properties apply to transverse test pieces. Impact-test location, specimen size and any requirement for mid-thickness specimens must be specified and assessed in accordance with the standard and the governing construction code.

Elevated-temperature behaviour

Minimum Rp0.2 for EN 10028-2 plate with t ≤16 mm
0.2% proof strength (MPa)50°C100°C150°C200°C250°C300°C350°C400°C450°C500°C
Minimum Rp0.2 for EN 10028-2 plate with t ≤16 mm273264250233213194175159147141

Specified minimum material properties; not allowable design stresses.

Thickness effect on high-temperature proof strength
Nominal thickness t, mmRp0.2 at 400°C, MPa min.Rp0.2 at 450°C, MPa min.Rp0.2 at 500°C, MPa min.
≤16159147141
>16 to 40156145139
>40 to 60150139134
>60 to 100139129123
>100 to 150127118113
>150 to 250121113108

The elevated-temperature proof-strength table explains the grade's value in boilers, pressure vessels, heat exchangers and pressure piping: it retains specified strength through 500°C under EN 10028-2. It does not establish a universal maximum service temperature. Design temperature is controlled by the construction code, design life, allowable stress, creep regime, oxidation or corrosion environment, weldments, cyclic loading and the actual product specification.

Selected EN 10028-2 Annex C creep reference data
Temperature1% creep strain, 10,000 h1% creep strain, 100,000 hRupture, 10,000 hRupture, 100,000 hRupture, 200,000 h
450°C216 MPa167 MPa298 MPa239 MPa217 MPa
500°C132 MPa73 MPa171 MPa101 MPa84 MPa
530°C84 MPa36 MPa102 MPa53 MPa45 MPa

Informative mean values derived with an indicated scatter band of approximately ±20%. They are not guaranteed acceptance properties and do not authorize continuous service at the listed temperatures.

Welding, forming and fabrication

16Mo3 is generally weldable by established fusion-welding processes, but it must not be treated as an ordinary structural carbon steel. The molybdenum addition and possible upper-range carbon content increase hardenability. Welding procedure qualification should address actual heat chemistry, combined thickness, restraint, heat input, hydrogen level, preheat, interpass control and any required post-weld heat treatment. EN 10028-2 refers welding practice to EN 1011-1 and EN 1011-2.

Fabrication controls that matter
IssuePractical requirement
Filler selectionUse a consumable qualified for the required weld-metal chemistry, room-temperature strength, toughness and elevated-temperature or creep duty. A generic carbon-steel filler should not be assumed acceptable.
Hydrogen crackingApply low-hydrogen consumables and controlled storage, joint cleanliness and thermal practice appropriate to thickness and restraint.
PWHTDetermine from the governing construction code and qualified procedure. Account for every fabrication, repair and shop heat-treatment cycle in the accumulated thermal exposure.
Hot formingControl finishing temperature and resulting condition. If forming changes or replaces normalizing, demonstrate the required final properties.
Cold formingConsider strain ageing, local thinning and the code requirement for subsequent heat treatment or property verification.
Dissimilar jointsBase filler selection and heat treatment on both materials, service temperature, carbon migration, creep compatibility and the applicable design code.
Machining and cuttingConventional methods are applicable, but flame-cut or heavily restrained edges should receive suitable thermal and quality control before welding.

Service limitations and supplementary testing

16Mo3 is not a stainless or inherently corrosion-resistant steel. General corrosion, high-temperature oxidation, sulfidation, erosion-corrosion and process-specific degradation must be evaluated independently. Its molybdenum content improves elevated-temperature mechanical performance but does not by itself establish suitability for a corrosive process environment.

Conditions requiring explicit specification or engineering review
ConditionWhat must be addressed
Sour H2S serviceEN 10028-2 permits HIC testing to be specified at enquiry and order. Select the test solution, acceptance class and any additional hardness or SSC requirements required by the project specification.
Pressurized hydrogen or high-temperature hydrogenAssess the material against the applicable hydrogen-service rules and operating envelope; designation 16Mo3 alone is not an approval for hydrogen service.
Low-temperature operationStandard plate toughness is specified only at +20°C. Required minimum metal temperature and impact test temperature must be established by the construction code.
Long-term creep serviceUse code-approved allowable stresses and weld-joint rules. Annex C creep data are informative and should not be inserted directly into a design calculation.
Multiple PWHT or repair cyclesAdvise the steelmaker of the intended time-temperature exposure and consider simulated heat-treatment testing where the EN 10028-2 Pcrit threshold will be exceeded.
CrMo embrittlement concernsWhere relevant to the operating environment and alloy system, specify any required step-cooling or other embrittlement assessment rather than assuming it is included.

Ordering and certification

Minimum information for a technically complete order
ItemWhat to state or verify
Product specificationThe exact product standard and edition, not only 16Mo3 or 1.5415.
Dimensions and tolerancesThickness or wall, diameter, width, length, dimensional standard and any restricted tolerance.
Delivery conditionFor example +N, including whether normalizing rolling is acceptable and whether simulated heat-treatment testing is required.
Inspection documentNormally an EN 10204 document appropriate to the equipment code and purchaser requirements, commonly type 3.1 where specified.
Mechanical testsRequired test temperature, orientation, specimen location, impact energy and elevated-temperature tensile tests.
Nondestructive examinationMethod, extent, acceptance level and whether it applies to parent material, welds or the finished component.
Supplementary service testsHIC, step cooling, hardness, simulated PWHT or other project-specific tests.
Fabrication historyIntended forming, normalizing, stress relief and the number and duration of anticipated PWHT cycles.
Regulatory requirementsApplicable pressure-equipment legislation, construction code, material approval route, marking and certification.

Check the certificate against the product standard actually ordered. A certificate showing 16Mo3 chemistry does not demonstrate compliance with a different product specification, delivery condition or construction code.

Substitution and cross-standard comparisons

Cross-reference tables frequently associate 16Mo3 with carbon-molybdenum ASTM or ASME materials. These comparisons are useful for identifying a similar application class, but they do not establish equivalence. The ASTM/ASME materials commonly compared with 16Mo3 can have higher molybdenum, different carbon limits, different thickness rules, different heat-treatment requirements and different mechanical-property or inspection bases.

A substitution review should compare the complete product specifications, dimensions, manufacturing route, chemistry, heat treatment, room- and elevated-temperature properties, toughness, creep data, weldability, certification and acceptance under the governing construction code.

Sources

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